You can easily count percentages using PROC FREQ with WEIGHT statement and then select those in the first third using LAG function:
proc freq data=state_counts noprint order=data;
tables state / out=state_counts2;
weight enrollment;
run;
data top3rd;
set state_counts2;
cum_percent+percent;
if lag(cum_percent)<100/3 then top_third=1;
run;