You are missing the ON criteria in your join between T0 and T4. I would rework your query as:
SELECT T0."REFID", T0."REFID_NR", T0."ID_POS",
CASE
WHEN T4."REFID" IS NOT NULL
THEN T4."REFID"
END AS "result"
FROM "SYSTEM"."T00_SOFT" T0
LEFT OUTER JOIN
(
SELECT T1."REFID", T1."REFID_NR", T1."ID_POS",T1."ARTIKEL" ,T2."VEHW", T2."VNHW" ,
(((T2."VEHW"*100)/(T2."VNHW"))*((T1."ER_AW"*100)))/(T1."BAS_AW") AS "claims"
FROM "SYSTEM"."T00_SOFT" T1
INNER JOIN "SYSTEM"."T00_EG" T2
ON T1."REFID" = T2."REFID"
AND T1."ORGID_WE" = T2."ORGID"
AND T1."ARTIKEL" = T2."MATNR" ) T4
ON T0."REFID" = T4."REFID"
You had joined T0 and T4 without describing how they were related. Remember, just because you defined how TOO_SOFT and TOO_EG are related in your subquery in the From clause does not imply how T0 and T4 are related. According to a reference manual I found here, join criteria are always required with Left and Right Outer Joins.
Also, I would hesitate to use a Case statement without an Else statement because if the case is not true then it will return NULL. If that's what you want, great, but I suspect you would benefit from programming in an alternative rather than leaving the Else statement out altogether.