C* collections are part of the CQL spec v.3. The only Java driver, that I'm aware of, supporting this spec completely is the open source DataStax Java driver. The driver offers 2 ways of working with CQL statements: one based on Statements/PreparedStatements/etc. and one using a fluent API.
If you are using Cassandra 1.2.x then look for the version 1.x of the driver. In case you are on Cassandra 2.0.x look for the version 2.0 of the driver (this is currently RC2, soon to go final).