Your application should be running and you need this code:
public boolean onKeyDown(int keyCode, KeyEvent event)
{
if (keyCode == KeyEvent.KEYCODE_VOLUME_DOWN || keyCode == KeyEvent.KEYCODE_VOLUME_UP) {
// Do your thing
return true;
} else {
return super.onKeyDown(keyCode, event);
}
}
List of keys: http://developer.android.com/reference/android/view/KeyEvent.html