This could be due to a timeout bug present in 7.33.0. There's a newer libcurl version out that you could use to see if it the bug remains or not.
It would also help if you would provide a smallish example source code here that shows how you do this so that we can see that the code is correct from your end. Or tell us if you can use one of the existing libcurl examples on the curl site to repeat the problem.