This will do it:
XmlNode node =
Doc.SelectSingleNode("/GC/DATA/CONTAINER/HEADER/ATTRIBUTE[@name = 'lang']/@value");
string SI = node.InnerText;
And I would advise using a null check:
XmlNode node =
Doc.SelectSingleNode("/GC/DATA/CONTAINER/HEADER/ATTRIBUTE[@name = 'lang']/@value");
string SI = null;
if(node != null)
{
SI = node.InnerText;
}