Twitter uses HTTPS exclusively now, so without setting up a MITM proxy, you will be unable to snoop on the data that is being transmitted.
With regards to setting up a MITM proxy, check out this piece of software: mitmproxy
If you're looking to send Tweets yourself, separately from Twitters web page / apps, check out their API: Twitter 1.1 API - statuses/update
Most browsers come with developer plugins, which will let you see what data is being sent by requests (including HTTPS requests). The best - in my opinion - is Chromes developer extension (which is installed by default), which can be opened by pressing 'F12'. Another alternative is Firebug for FireFox, which once installed can also be opened by pressing 'F12'.
Further more, perhaps you should add a bit more context to your post, such as what platform you're interested in, such as Android, iPhone, or Web (i.e. Twitters vanilla website).