I think you need to query the ApplicationDbContext for it as there's no obvious way to get it with a single call from the UserManager
or UserStore
APIs...
var context = new ApplicationDbContext();
var roles = await context.Users
.Where(u => u.Id == userId)
.SelectMany(u => u.Roles)
.Join(context.Roles, ur => ur.RoleId, r => r.Id, (ur, r) => r)
.ToListAsync();