The nth-child syntax isn't complex enough to allow for what you want.
In your example however, you can write
tr:first-child, tr:nth-child(2n+4)
for a selector.
This means use the first child, and also every even child starting at the fourth.
See updated fiddle.
It's not an ideal solution; you don't have any control over the openingTimes
class any more, but I can't think of any solution where you do. Sorry!