Plotted as Scatter with Smooth Lines:
Format the x-axis Major unit to Fixed 0.125 to show 3-hourly intervals (any more detail and the chart would be very cluttered).
@Jon Peltier (who knows all there is to now about Excel charts and MORE) has made the point that smooth lines may be misleading. (Inadvertently I provided an example of just that here!) So a slightly simplified version with straight lines for the sake of a better answer for the OP and also for comparison:
with straight and smooth overlaid: