You can try this page: http://www.webpagetest.org/ it measures the performance of your generated output (html).
Everything else like slow php execution times cannot be measured by observing the frontend properly. You will have to gain some skills and tools to profile your php application and see what is actually slow. The standard procedure is googling for optimizing php scripts
or profiling a php script
, etc. You probably will need to invest money to get some proper tools.
PHP must not even be the culprit here. Long server response, bad mysql queries, etc may impact execution and delivery speed.