It is not really possible to tell directly whether or not the Master Method works for some logarithmic function. This would depend on the specific recurrence you're trying to solve. It all depends on how f grows in comparison to nlogb a.
In the example given by JPC (where T(n) = 4T(n/2) + log(n)), it is indeed possible. However, also consider the example T(n) = 2T(n/5) + log(n). In this recurrence it is harder to determine whether nlog5 2 grows faster than log(n). If the logarithmic function f(n) gets more complex (e.g. log3(n/2)), it becomes even harder.
In short, it may be hard to determine for logarithmic functions how they grow when compared to an exponential function when the exponent is less than 1 (for exponents >= 1, log(n) is always faster). If it doesn't seem to work for you, you'll have to use other techniques to solve the recurrence.