The getting started guide says this:
"Also, you must set the content-type header to application/x-www-form-urlencoded when sending data as form fields."
So you may be out of luck I'm afraid. You may be able to get a handle to the underlying http request and access the request body like that, but it'd be a fair amount of work. What's the reasoning behind using multipart forms? I'd guess at file upload, but I'd be interested to know whether there's another use case.
It looks like file upload itself will work in REST using regular CFFile handling. If you can handle placing other parameters on the URL, you may get something workable.