You are right, this add_attribute is not present now. Looks like you need to use update_item api on boto.dynamodb.layer1.
Adding a working code - I tried on DynamoDB local:
conn.update_item(
"table-1",
{"firstKey":{"S":"12345"}},
{"counter":{"Action":"ADD","Value":{"N":"1"}}}
)
Here it increments counter by 1 on table which has "firstKey" as the Hashkey.