It is possible to construct a correct generator without having to remember all previously generated codes. You can generate serial numbers that are spaced 6 characters apart by using Hamming code. A hamming code can be designed to arbitrarily space out two distinct generated values. Obviously, the greater the distance, the higher redundancy you will have to use, resulting in more complex code and longer numbers.
First you design a hamming code to your liking, that encodes a number into a sequence of hexadecimal digits and then you can take any sequence of numbers and use it as a seed, such as prime numbers. You just always need to remember, what number was used last and use the next one.
That being said, if you don't need to properly ensure minimal distance of two serials, and would settle for a small error, I would suggest that any half decent hash function or cypher should produce decently spaced out outputs. Therefore the first thing I would try to do is to take MD5 or SHA hashes and test-drive them on numbers 1 - 1000. My hopes are, the results will be quite satisfactory.