As you are using Raphael JS, the easiest way to do this is to hook into the hover method that Raphael supplies out of the box and update it that way.
$(document).ready(function() {
var rsr = Raphael(0, 0, 1000, 1000);
var path_cz = rsr.path("M513.4,537l-329,19.3L209.5,666c0,0,9.5,36.8,51.5,48.8l108,22.7c13.3-16.7,119-43.4,175.6-8.7l165.7-58.6 c0,0,210.2-54.5,113.6-150.5c-33.3-27.3-61.9-50.4-61.9-50.4l-72.8-5.5l-46.9,2l-154,6.7l-2.6,21L513.4,537z").attr({fill: '#4F217C',parent: 'farver','stroke-width': '0','stroke- opacity': '1'}).data('id', 'path_cz');
path_cz.hover(function() {
path_cz.node.setAttribute('class', 'one');
}, function() {
path_cz.node.setAttribute('class', 'two');
});
});
For an example, here is a fiddle: http://jsfiddle.net/n9Mt6/1/