I never worked on Windows 8/8.1 apps, so maybe there is some integrated feature to do what yout want, but I didn't find anything on that subject. In fact, what I found seems to indicate the opposite :
If you want the data of your Windows Store app to be secured, you have to do it by yourself.
Depending on the desired level of security you could try using some form of encryption for your local files. This would make the settings unreadable by the user, and prevent them to tamper with it.
But as pointed in Windows 8 Apps - Local Storage Security, encryption might not be the best way if you really want to make sure the data cannot be edited outside your app, since it is possible to extract the key from your app and decode the data.