It's a sampling profiler, so it only shows you the calls that were executing when it sampled; you can't see every call that happened over a period of time. That said, you can see the call-stack that leads up to every call, if you show the 'Extended Detail Pane' over on the right, which may give you a good idea what happened. See the Apple documentation.
As an alternative solution, see How to log all methods used in iOS app