Here's the doc page for CollectionViewSource for winrt: http://msdn.microsoft.com/en-us/library/windows/apps/windows.ui.xaml.data.collectionviewsource.aspx
The GroupDescriptions property is not available in WinRT
If I remember correctly this should work for you:
<CollectionViewSource x:Name="groupedAppointments" IsSourceGrouped="True"
ItemsPath="ThePropertyThatIsGroupedByDateOfVisitGoesHere"
d:Source="{Binding Appointments,
Source={d:DesignInstance Type=dataModel:SampleDataSource,
IsDesignTimeCreatable=True}}">
</CollectionViewSource>