The built-in operators are specified in 5.10:
The == (equal to) and the != (not equal to) operators have the same semantic restrictions, conversions, and result type as the relational operators except for their lower precedence and truth-value result.
This defers the specification to that of the relational operators in 5.9; for enumerations that's specified by 5.9/5:
If both operands (after conversions) are of arithmetic or enumeration type, each of the operators shall yield true if the specified relationship is true and false if it is false.
So, as one might expect, the comparison operators are applicable to enumerations, comparing the numeric values.