If your using with Firewalls (IPTABLES) Please specify the Port in which Mysql server is listening on.
The following rule will provide specific network only will be listening on Only the 192.168.100.0/24 network people can access your mysql. Here i have specified the default mysql port 3306
iptables -A INPUT -i eth0 -p tcp -s 192.168.100.0/24 --dport 3306 -m state --state NEW,ESTABLISHED -j ACCEPT
To DROP IP Address
iptables -A INPUT -i eth0 -p tcp -s 206.xxx.xx.xx --dport 3306 -m state --state NEW,ESTABLISHED -j DROP