In the binary tree there are n nodes. We know that the order of the nodes cannot be changed. Each of the nodes are labelled with a number {1...n}. Lets assume n=4 and the label current root of the tree is 1. how many other possible roots can you have?
The only alternatives are 2,3,4 Therefore on the tree, there are only N-1 more roots the tree can have and only N-1 unique rotations. May not be a theoretical explanation but I hope this helps you visualize it.