MAC addresses doesn't get routed, so the IP address would have to be of a host on your network. You will have to ping the IP address first and then use arp -a
; like
ping <Remote_IP_Address>
arp -a <Remote_IP_Address>
See this related posts here
is-there-a-way-to-find-the-mac-address-of-a-remote-machine-i-have-connected-to-w