You can not implement it using PHP.
PHP is hosted in server while website is displayed in client side. Communication with thumb scanning device has to be done in client side.
As far as I know it can not be done using HTML5, so you are left with 3 options
- Flash
- Java
- COM (Windows only
I am not sure about Flash and COM but you can definitely use JAVA to interact with thumb scanning device. It will send back the scanned information to server which can be used to validate user.
Note that validation is server side and can be written in PHP