In Notepad++, set the "Regular expression" radio button and put this in the "Find what" box:
^\s*
And leave the "Replace with" box empty.
You'll have to read about "regular expressions" to get all the details, but for the above:
^ means only match at the beginning of the line
\s means match any whitespace char (including space and tab)
* means to match zero or more of the preceeding
So, in English, it says "match zero or more whitespace chars at the beginning of the line".