The Multimedia module uses plugins that are different on each platform (or compiler).
See http://qt-project.org/wiki/Qt_Multimedia_Backends
On Windows you have DirectShow and MediaFoundation (WMF). Only the WMF plugin implements audio decoding features. WMF plugin is only available with MSVC compiler.
See http://qt-project.org/doc/qt-5.1/qtmultimedia/platform-notes-windows.html