There's 2 errors in your XSLT:
Your
<Styles>
are outside of any template, they will not appear in your output document at all. They need to be inside Workbook.Cell does not have an
ss:ID
attribute only Style has ss:ID, to reference the Style usess:StyleID="s62"
instead.
Take a look inside c:\Users\uname\appdat\microsoft\windows\temporaryInternetFiles\content.MSO\xxxxxxxx.log (you cannot browse to that location, the folder is hidden, so copy that path into your explorer Adressbar or in a "Run" window) it would have given you some more information like:
XML ERROR in Table
REASON: Illegal Tag
FILE: C:\temp\Untitled15.xls
GROUP: Row
TAG: Cell
ATTRIB: ID
VALUE: s62
Office throws notoriously bad error messages but that and looking in you result document should usually give you some clue.