Yes. You have confused the parameters of the Add method. The first parameter is the target namespace, with the second being the URI. So your code should look like this:
_schemaUri = @"L:\schemaDoc.xsd";
XmlSchemaSet schemas = new XmlSchemaSet();
schemas.Add(_targetNamespace, _schemaUri);
Refer to the documentation for more details:
http://msdn.microsoft.com/en-us/library/1hh8b082%28v=vs.110%29.aspx