I solved it using the following code and set the project trigger to "On form submitted" so that it runs each time a new response is submitted.
function setDefault() {
var ss = SpreadsheetApp.getActiveSpreadsheet();
var sheet = ss.getActiveSheet();
var lastRow = ss.getLastRow();
for (var i = 3; i <= lastRow; i++)
{
sheet.getRange('A' + i).activate();
sheet.getActiveCell().offset(0, 5).activate();
sheet.getActiveCell().setValue("Unknown");
sheet.getActiveCell().offset(0, 1).activate();
sheet.getActiveCell().setValue("New");
}
};