The answer is really in my comment, but it needs a bit of elaboration. To restate from the comment...
The first predicate of the where clause has to uniquely identify the partition key. In your case, since the primary key is only one column the partition key == the primary key.
Cassandra can't do range scans over partitions. In the language of CQL, a partition is a potentially wide storage row that is uniquely identified by a key. In this case, the values in your nos column. The values of the partition keys are hashed into tokens which explicitly identify where that data lives in the cluster. Since that hash has no order to it, Cassandra cannot use any operator other than equality to route a statement to the correct destination. This isn't a primary key index that could potentially be updated, it is the fundamental partitioning mechanism in Cassandra. So, you can't use inequality operators as the first clause of a predicate. You can use them in subsequent clauses because the partition has been identified and now you're dealing with an ordered set of columns.