The new AdMob's AdView
(included in Google Play Services) doesn't have testDevices
attribute in XML. Check the documentation.
You need to add your test devices in the code:
AdRequest.Builder adRequestBuilder = new AdRequest.Builder();
adRequestBuilder.addTestDevice(AdRequest.DEVICE_ID_EMULATOR);
adRequestBuilder.addTestDevice("xxxxxxxxx");
adView.loadAd(adRequestBuilder.build());