The definition of fst
is
fst :: (a, b) -> a
fst (a, _) = a
and the definition of (.)
is
(.) :: (b -> c) -> (a -> b) -> a -> c
(f . g) = \x -> f (g x)
If we use these definitions to expand your function, we get
f' xs = map ((+8) . fst) xs
f' xs = map (\x -> (+8) (fst x)) xs -- definition of (.)
f' xs = map (\x -> (+8) ((\(a, _) -> a) x)) -- definition of fst
f' xs = map (\(a, _) -> (+8) a) -- we can move the pattern matching
f' xs = map (\(a, _) -> a + 8) -- expand section