I ended up breaking it all out like this:
XDocument doc = new XDocument();
XElement songsElement = new XElement("Songs");
foreach(var musicfile in musicfiles)
{
XElement songElement = new XElement("Song");
string songTitle;
try { songTitle = (TagLib.File.Create(musicfile).Tag.Title); }
catch { songTitle = "Missing"; }
uint songTNint;
try { songTNint = (TagLib.File.Create(musicfile).Tag.Track); }
catch { songTNint = 00; }
string songTN = songTNint.ToString();
string songPath = musicfile;
string songArtist;
try {songArtist = (TagLib.File.Create(musicfile).Tag.Performers[0]);}
catch {songArtist = "Missing";}
List<string> songGenres = new List<string>();
foreach (string Genre in (TagLib.File.Create(musicfile).Tag.Genres))
{ songGenres.Add(Genre);}
string songGenre;
if (songGenres.Count > 1) { songGenre = (songGenres[0] + "/" + songGenres[1]); }
else { try { songGenre = songGenres[0]; } catch { songGenre = "Missing"; } }
songArtist = Regex.Replace(songArtist, @"[^\u0020-\u007E]", string.Empty);
XElement titleElement = new XElement("Title",songTitle);
XElement tnElement = new XElement("TN", songTN);
XElement pathElement = new XElement("Path", musicfile);
XElement artistElement = new XElement("Artist",songArtist);
XElement genreElement = new XElement("Genre", songGenre);
songElement.Add(titleElement);
songElement.Add(tnElement);
songElement.Add(pathElement);
songElement.Add(artistElement);
songElement.Add(genreElement);
songsElement.Add(songElement);
}