Consumer OneDrive isn't intended for business use and sharing a single OneDrive account for multiple people isn't recommended either. You should look into OneDrive for business for your scenario: https://onedrive.live.com/about/en-us/business/.
OneDrive for Business uses the SharePoint developer APIs: http://blogs.msdn.com/b/sharepointdev/archive/2013/08/13/access-skydrive-pro-using-the-sharepoint-2013-apis.aspx