I have found a solution by myself. Unison doesn't seem to be a solution for the problem.
Now i'm using my raspberry pi and sshfs to mount the two directories of the NAS. Then i wrote a script, which searches for changes between the two folders. After detecting the changes i use wget to copy from one directory to the other. This also has the positive effect that the raspberry pi doesnt load the whole file at once, but only the part which is currently needed for the copy. So it loads with 500 kb/s and puts the file on the remote NAS with 500 kb/s.
Problem solved, thanks anyway