It is fairly easy to learn basic data modeling, and with that you can use any relational database you like (or even apply the techniques to NoSQL or Document databases too). I wrote a series of articles for WebAndPHP Magazine last year that you can refer to, these cover the basics and should get you started. Here is a preview of one of the articles you can start with, there are others available if you search the site:
http://webandphp.com/DataModelling101
This is a PDF magazine, I think you can still download old issues (you need to register).
There are many other sources on the Web as well, if you search for "entity relationship modeling tutorial" you will find lots of good content.