You're probably going to want to use a list for this.
If you really want to keep it the way you're doing it, you can do this:
a1 = a2 = a3 ... = i9 = 0
or to save some writing space
#(0,)*81 is the same thing as writing 0, 0, ..., 0
a1, a2, a3, ..., i9 = (0,)*81
but I suggest you use a list of lists.
Here's a list comprehension that creates a list of 9 zeros:
a = [0 for x in range(9)]
Use this idea to create a list comprehension that creates a list of 9 lists.
grid = [[0 for x in range(9)] for y in range(9)]
Then you can access grid like so:
>>> print grid[0][0]
>>> 0
>>> print grid[8][8]
>>> 0
>>> print grid
>>> [[0, 0, 0, 0, 0, 0, 0, 0, 0],
[0, 0, 0, 0, 0, 0, 0, 0, 0],
[0, 0, 0, 0, 0, 0, 0, 0, 0],
[0, 0, 0, 0, 0, 0, 0, 0, 0],
[0, 0, 0, 0, 0, 0, 0, 0, 0],
[0, 0, 0, 0, 0, 0, 0, 0, 0],
[0, 0, 0, 0, 0, 0, 0, 0, 0],
[0, 0, 0, 0, 0, 0, 0, 0, 0],
[0, 0, 0, 0, 0, 0, 0, 0, 0]]