When you reverse-resolve an IP it will come back to it's PTR record in the zone, which there is only one. So for example www.google.com
Non-authoritative answer:
Name: www.google.com
Addresses: 2607:f8b0:4007:800::1010
74.125.224.242
74.125.224.244
74.125.224.240
74.125.224.241
74.125.224.243
but 74.125.224.242 reverse resolves back to:
Name: lax04s08-in-f18.1e100.net
Address: 74.125.224.242
and not www.google.com.
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The apache server itself listens on an ip address independent of the hostnames attached to the ip, using the Listen directive in the config file. Apache just wants to hear data coming across port 80 on that IP.
Listen *:80 <-- listen on all adapters (127.0.0.1 and all network IPs)
or
Listen AAA.BBB.CCC.DDD:80 <-- listen on a specific adapter..
When you set up your virtual hosts Apache is able to pull the hostname from the headers and send it over to the right DocumentRoot to handle the pages you are presenting with that hostname.
Example:
<VirtualHost *:80>
ServerName www.server.com
ServerAlias server.com
DocumentRoot "c:\htdocs\wwwroot"
</VirtualHost>
<VirtualHost *:80>
ServerName www.server2.com
DocumentRoot "c:\htdocs\wwwroot2"
</VirtualHost>
Hope this helps.