Your password is saved after hashing on database. So, you need to rehash you password before doing any find operation.
public function login()
{
$username=$this->request->data['username'];
App::uses('SimplePasswordHasher', 'Controller/Component/Auth');
$passwordHasher = new SimplePasswordHasher();
$password = $passwordHasher->hash($this->request->data['password']);
$msg = $this->Employee->authenticateUser($username,$password);
......
//rest of your code
....
And last I have to mention that you should use AuthComponent
for login system.