Just add an ApplicationSettings entry to your config file
<MyApp.Properties.Settings>
<setting name="MyServiceUrl" serializeAs="String">
<value>http://a.b.com/ServicioWeb.svc</value>
</setting>
</MyApp.Properties.Settings>
Now, every time you need to call the service write
Using wcf = New ServicioClient("BasicHttpBinding_IWCF_ServicioWeb",
New EndpointAddress(YourAppNameSpace.Properties.Settings.Default.MyServiceUrl))
.... call your wcf methods ....
End Using