SELECT Employee,Jobnum,city ,[state], [Datetime], [Action]
FROM (
select Employee,Jobnum,city ,[state], [Datetime], [Action]
,ROW_NUMBER() OVER (PARTITION BY Employee,Jobnum ORDER BY [Datetime] DESC) AS rn
from EmployeeData
) Sub
WHERE rn = 1
Note
Avoid using Sql Server Key words for your column names, if you do have any column names which are key words in sql server use square brackets []
around them.