One of several approaches,
C = A(~ismember(A(:,1),B),:);
Note that you need to be very careful when comparing floating point numbers for equality, and depending on how your dates have been created you might find that any direct comparison approach doesn't quite do what you expect.
E.g.
(0.3-(0.2+0.1))==0
ans =
0
is correct to double precision, but often surprises people.