You can use a cte + Row_Number
to take only the first (complete) row of each group:
WITH CTE AS
(
SELECT Email, IP, Country
, RN = ROW_NUMBER() OVER (PARTITION BY Email ORDER BY Email)
FROM dbo.Emails
)
SELECT Email, IP, Country
FROM CTE
WHERE RN = 1
Change the ORDER BY
if you want a specific row.