magento default config values for storeview

Question

I understand that you can set default store config values by using the syntax

<default>
    <path>
        <to>
            <config>value</config>
        </to>
    </path>
</default>

but i am also pretty certain that it is possible to set default values for individual store views in config.xml also . Without the need to set manually in admin or by using an upgrade script.

Is it possible?

I have tried

<storecode>
    <path>
        <to>
            <config>value</config>
        </to>
    </path>
</storecode>

but that didnt work