the largest positive is 0111 1111 = 127
128 | 64 | 32 | 16 | 8 | 4 | 2 | 1 |
0 | 1 | 1 | 1 | 1 | 1 | 1 | 1 |
The largest Negative byte is 1000 0000 = -128
-128| 64 | 32 | 16 | 8 | 4 | 2 | 1 |
1 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
In binary the MSB(Most Significant Bit - the front one) is reserved to signify a negative number. The concept is called Twos' Complement and is used by most computers as a way of representing integers in binary(base 2) notation.
To get more info look into binary calculations