If you are not seeing the option in the build log, that means whatever setting you edited is not being propagated to the final "resolved" value. Xcode uses a cascading level system for its build settings. And it consists of these levels:
iOS Default Settings -> Project Settings -> Target Settings -> Final Resolved Setting
(Not to mention the .xcconfig files, but I'm guessing you don't have those)
If you are setting your path at the Project level, then there may be Target-level path that's overriding it. In the Xcode "Build Settings" window, make sure you select the "Levels" tab, so you can see all the settings of each level, with the left-most one being the final Resolved value.
Then there are the per-configuration settings, where you can set a different value for Debug vs Release builds. Make sure you're setting it right for the configuration you are running.