If you have the URL directly in the address bar it would be a GET request for which you can handle a different behaviour e.g. GET is prohibited for this URL or render the blank form for the User on the submission of which the POST method will be called upon.
@RequestMapping(value = "/save", method = RequestMethod.GET)
public ModelAndView saveUser(@ModelAttribute("user") User user, BindingResult result){
userService.addUser(user);
}