The solution is to update the version of AIR used within your SDK. Those new icon sizes are not supported in the version of AIR included in Adobe Flex 4.6 [or Apache Flex 4.8].
Instructions for updating the AIR SDK within Flex can be found here. Generically do this:
- Download current SDK and unzip it
- Copy and files and folders from your unzipped directory to the root of your Flex directory
- Update the name of the Flex SDK in the “flex-sdk-description.xml” file.