Not sure why the original PV was created with only part of the capacity of the underlying /dev/md2
device, but this should resize the PV to use the full capacity:
pvresize /dev/md2
You could also use that to only partially extend the PV, or even to shrink it, I think, provided you make sure that the portion you're removing is not currently allocated to any LVs. The manual page for pvresize
should have more information on the options you may need for each scenario.