This is equivalent to:
pSpiTxBuf[0] = CC2520_INS_SFLUSHRX; // get rid of this packet
pSpiTxBuf[1] = CC2520_INS_SFLUSHRX; // double flush [CC2520 Bug#1]
(which would probably have been a clearer way to write the code in the first place).
i.e. it just sets two adjacent register values to CC2520_INS_SFLUSHRX.